Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant

A new dithiocarbamate-type heavy metal precipitant, sodium 1,3,5-hexahydrotriazinedithiocarbamate (HTDC), was prepared and used to remove coordinated copper from wastewater. In the reported dithiocarbamate-type precipitants, HTDC possesses the highest percentage of the effective functional groups. It could effectively precipitate copper to less than 0.5 mg l⁻¹ from both synthetic and actual industrial wastewater containing CuEDTA in the range of pH 3–9. UV–vis spectral investigation and elemental analysis suggested that the precipitate was a kind of coordination supramolecular compound, [Cu₃(HTDC)₂]_n. The toxicity characteristic leaching procedure (TCLP) and semi-dynamic leaching test (SDLT) indicated that the supramolecular precipitate was non-hazardous and stable in weak acid and alkaline conditions. Tests of an anion exchange resin D231 provided a clue to simultaneously remove excess HTDC and residual CuEDTA in practical process of wastewater treatment.     

紫外分光光度法在水中阴离子表面活性剂标准样品研制中的应用

研究了阴离子表面活性剂水溶液的紫外吸收特性，并将研究结果用于阴离子表面活性剂水质标样的稳定性，均匀性和定值工作，简化了操作手续，获得了准确的分析结果。     

Chlorinated and brominated organic contaminants in fish from Shanghai markets: a case study of human exposure

In the present study were two favorite edible fish species for local residents, i.e., mandarin fish and crawfish, collected from the Shanghai market and analyzed for selected organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), hexabromocyclododecane (HBCDD), polybrominated diphenyl ethers (PBDEs) and methoxylated PBDEs (MeO-PBDEs). Efforts were also made to identify the potential sources of these contaminants. Comparable concentrations of hexachlorocyclohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs) and HBCDD were found in muscle tissue of mandarin fish from Guangdong (GDF), the Pearl River Delta and from Taihu Lake (TLF), the Yangtze River Delta. Levels of chlordanes, PCBs and PBDEs were about one magnitude lower in TLF compared to GDF. The concentrations of OCPs in the butter-like gland of the crawfish (CFB) were 2-5 times of those in the crawfish muscle (CFM) while concentrations of PCBs, PBDEs and MeO-PBDEs were comparable. The different patterns and levels of chlorinated and brominated organohalogen contaminants seen in mandarin fish from GDF and TLF indicates that different types of chemicals might be used in the two delta regions. The present study also shows a good correlation between the concentrations of hexachlorobenzene (HCB) and pentachloroanisol (PCA) in fish for the first time. Fish consumption limits based on chemical contaminants with non-carcinogenic effects were calculated. The estimated maximum daily consumption limit for GDF, TLF, CFM and CFB were 1.5, 2.6, 3.7 and 0.08 kg, respectively, indicating no significant risk regarding the persistent organic pollutants measured in the present study.     

南方土壤酸沉降敏感性研究Ⅷ.盐基离子淋溶的多因素分析

在模拟酸雨条件下土壤盐基离子淋溶特性研究的基础上，采用生成分分析及多元回归分析方法研究了土壤盐基淋溶的影响因子．结果表明，通过主成分分析方法可将选取的15个原始变量综合成为2个主成分，为进一步分析盐基释放量与土壤理化性质之间的关系提供了方便．影响盐基释放量的主要因子有土壤原始pH值、可交换性盐基含量、蒙脱石含量、活性氧化物、1.4nm矿物等，它们表现出效应，而高岭石和可交换性铝含量表现出负效应．利用主成分分析的结果进行多元回归分析，可得到土壤累积盐基释放量与2个主成分之间的回归方程．     

国家《大气污染防治行动计划》健康效益评估

为了提高空气质量改善进程,2013 年国家发布了《大气污染防治行动计划》。本文基于空气污染与健康效益评估模型(BenMAP),对人口分布资料、大气污染与人体健康影响的暴露反应关系等进行了本土化修正,采用“支付意愿法”与“疾病成本法”相结合的方法,系统评估了《大气污染防治行动计划》实施后,PM_2.5 污染变化引起的环境健康效益。研究结果表明,《大气污染防治行动计划》的实施将在一定程度上降低PM_2.5 环境浓度,改善环境空气质量。如果《大气污染防治行动计划》空气质量目标全面实现,可以避免城镇8.9 万居民的过早死亡,减少12 万人次住院治疗以及941 万人次的门诊和急诊病例,实现的全国健康效益约为867 亿元/ 年,说明了《大气污染防治行动计划》实施的健康有益性。本文对政府部门开展污染损失评估及制定环境健康政策具有重要的参考价值。     

长江流域春夏旱涝灾害与太平洋海温关联性研究

基于长江流域区域1956-2011年50年气象资料和同期太平洋海温资料,采用Z指数、EOF、REOF、SVD分析等方法,探讨长江流域春季和夏季旱涝特征及其旱涝事件与极端海温异常之间的关联性,得出以下结论。1REOF的Z指数春夏季节旱涝空间分区特征显示,春季前6个模态的累计方差贡献率能够达到61.2%,收敛速度较平缓,夏季前6个模态累积方差贡献率更低,只有52.1%。2前冬太平洋海温的变化与长江流域旱涝的态势呈显著相关关系,春季海温场与长江流域旱涝Z指数场的SVD第一模态显示,长江流域的东北区的旱涝与厄尔尼诺显著相关,当赤道东太平洋海温升高,西太平洋海温降低时,长江流域东北地区偏涝,而长江流域的西部地区偏旱,反之亦然。3夏季海温场与长江流域旱涝Z指数场的SVD第一模态,表明太平洋海温分布主要呈现南北向的分布,当赤道中东太平洋海温偏高,北太平洋海温偏低时,长江流域夏季中部地区偏涝。反之亦然。第二模态,全球海温呈现厄尔尼诺类型的分布,中东太平洋是负相关,而在西太平洋为显著负相关。     

Analysis of trace dicyandiamide in stream water using solid phase extraction and liquid chromatography UV spectrometry

An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction. The extraction procedure (including loading, washing, and eluting) used a flow rate of 1.0 mL/min, and dicyandiamide was eluted with 20 mL of a methanol/acetonitrile mixture (V/V = 2:3), followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography–ultraviolet spectroscopy (HPLC–UV). Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge (with activated carbon). Separation was achieved on a ZIC^®-Hydrophilic Interaction Liquid Chromatography (ZIC-HILIC) (50 mm × 2.1 mm, 3.5 μm) chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions (R² > 0.999). Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations (RSDs, n = 3) were below 6.1% with a detection limit of 5.0 ng/mL for stream water samples.     

纳污湿地上覆水中重金属的监测及评价

以武河湿地为研究区域采集上覆水水样,采用ICP-AES法测定湿地水体中重金属的含量,参照有关标准用水质标准级别法对水中重金属污染情况进行了评价。结果表明:武河湿地中重金属Hg污染十分严重,各采样点均有分布且水质属劣Ⅴ类。重金属元素Cd污染并不严重,总体水质较好。重金属元素As、Cr、Cu、Pb在武河湿地中污染较轻近乎无污染,水质为Ⅰ类。由于重金属Hg的污染十分严重所以研究区内综合质量等级在4以上,水质为Ⅴ类和劣Ⅴ类,污染严重。